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Poisonous Gases
The gases on this list are either on the Department of Transportation's Category 1 list, or the Linde Specialty Gases company's Group 6 - Very Poisonous list. These chemicals are highly toxic gases at ambient temperature and pressure. They have an extremely high potential for causing significant harm if not adequately controlled.
| Arsine | Boron trichloride | Chlorine pentafluoride |
| Chlorine trifluoride | Cyanogen | Cyanogen chloride |
| Diborane | Dinitrogen tetroxide | Fluorine |
| Germane | Hydrogen selenide | Nitric oxide |
| Nitrogen dioxide | Nitrogen trioxide | Nitrosyl chloride |
| Oxygen difluoride | Phosgene | Phosphine |
| Phosphorus pentafluoride | Selenium hexafluoride | Stibine |
| Sulfur tetrafluoride | Tellurium Hexafluoride | Tetraethyldithiopyrophosphate |
| Tetraethylpyrophosphate |
Guidance: Departments may choose to add other chemicals to the above list. For example, sulfur-containing compounds such as mercaptans can cause significant odor problems when used in the laboratory. Pre-approval of the conditions under which they can be used may prevent odor complaints.

